三江源地区高寒草地土壤功能的水平分异特征及其沿发生层的垂直变化

三江源地区是研究土壤生态系统功能响应气候变化的热点区域.为了研究三江源地区高寒草地土壤剖面功能特征和驱动机制沿发生层的差异,分析了高寒草地土壤剖面不同发生层的土壤功能指标(包括呼吸、氮转化速率和酶活等)以及与环境因子之间的相关关系.结果表明,土壤功能特征在高寒草甸和高寒草原之间不存在显著差异,表层土相比于深层土具有更高的呼吸、氮转化速率和酶活.土壤理化性质中全氮含量是不同发生层土壤功能特征的关键驱动因子,分别解释了土壤功能特征18.3%、21.4%和27.5%的水平分异.气候和植被因子主要在表层土中通过改变土壤理化性质间接影响土壤功能,但是大气氮沉降在深层土中对土壤功能仍存在影响.结果显示,三江源地区高寒草地土壤表现出显著的氮受限特征,为全球气候变化背景下土壤功能多样性的维持和对气候变化的响应提供了新的见解.     

快速工业化区域建设用地问题与制度优化研究——以佛山市南海区为例

快速工业化区域是工业化快速发展、工业化水平迅速提升、经济社会结构急剧变化的新兴地域类型。普遍存在着建设用地总量急剧扩张、空间无序分散、城乡缺乏统筹等问题。本文从佛山市南海区典型案例入手，运用新制度经济学原理。归纳和解析了快速工业化区域城乡建设用地的主要问题，认为双二元管理体制、农村土地产权不完善、城乡土地市场发育不平衡和部门规划不协调等是建设用地发展的主要体制性障碍因素，并从管理、产权、市场、规划等方面系统提出相应的制度优化对策。     

Time-series analysis of global zinc demand associated with steel

This study aimed to analyze the global-scale substance flow of zinc associated with steel in order to discuss the sustainable use of zinc resources in the future. The relationship between the demand for steel and zinc was characterized in terms of zinc intensity for galvanized steel and the percentage of galvanized steel that accounts for the total steel demand. Zinc consumption for steel was divided into end uses according to the statistics on steel. Zinc demand in the future was forecasted with three scenarios for zinc intensity. Future steel demand was estimated using the stocks-drive-flows model, in which the demand is determined by the change in stock. The growth of in-use stock of galvanized steel in the future was estimated by considering economic growth on the basis of the transition of in-use stock of galvanized steel in the past. The cumulative zinc demand for galvanized steel up to the year 2050 was compared with the zinc reserves. It was found that the global average recovery rate of zinc was estimated at approximately 20% by the dynamic substance flow analysis for zinc. It is hoped that the recovery rate will increase. Even if zinc intensity is continuously reduced according to an experience curve based on technological development, a large portion of the current reserves will be consumed for galvanized steel. It was concluded that technological development in reducing zinc intensity will play a significant role in zinc resource conservation.     

东北典型黑土区耕地轮作休耕的空间重构

轮作休耕是保障黑土区耕地资源可持续利用的重要手段。科学合理确定粮食作物轮作休耕的耕地利用规模及空间分布,对实现黑土区耕地修养生息、提升地力和平衡粮食供求结构具有重要意义。以东北典型黑土区——克山县、拜泉县和依安县为研究区,运用作物种植空间适宜性评价模型、多目标优化（MOP）模型和智能体土地布局优化配置（AgentLA）模型,基于地块尺度构建耕地轮作和休耕布局,适度调整轮作休耕规模及分布。结果发现：（1）研究区主要作物种植适宜性高值和低值区存在明显空间差异。玉米和大豆种植适宜性高值区交汇于依安县北部和克山县西部,是玉米—大豆轮作优势区域。主要作物种植适宜性低值区交汇于依安县南部和拜泉县西南部,是休耕的重点区域。（2）基于种植结构优化的轮作规模实现了大豆种植比例增加和玉米种植比例减少,缓解了目前玉米阶段性供大于求、大豆供给不足的现实矛盾。通过设定多种粮食供求情景确定休耕规模有利于灵活应对粮食市场变动。（3）兼顾耕地空间适宜性和集聚性的轮作休耕布局有利于充分利用耕地资源禀赋比较优势、发展规模化经营,对提高耕地利用效率具有重要作用。研究通过科学重构黑土区耕地轮作和休耕空间布局,实现了耕地空间适宜性、空间集聚性、种植结构合理性和粮食供求稳定性的同步提升,为实现黑土区耕地资源合理可持续利用和粮食安全提供政策参考。     

长三角地区生态城镇化空间格局及影响因素

生态城镇化作为新型城镇化的重要组成部分,是生态文明理念的具体实践。以长三角地区41个城市为研究区域,构建区域生态城镇化指标体系,测度2000—2018年生态城镇化的发展水平,探究生态城镇化指数的时空演化特征及影响因素的作用机制。结果表明：（1）长三角地区生态城镇化水平整体呈上升趋势,高值区逐渐在浙江集聚,低值区在江苏北部和安徽北部集中,各城市生态城镇化指数差距逐渐缩小,区域生态一体化程度不断提高。（2）长三角地区生态城镇化水平的空间自相关性逐渐增强,其空间演化具有较强的变动性、依赖性和整合性,变动性自西至东逐渐减弱,依赖性自西北至东南逐渐增强。（3）财政投入水平、城乡收入差距、工业发展水平、土地投资强度、人口密集程度和科技发展水平对长三角地区生态城镇化水平的影响依次降低,在众多因素的综合作用下,各城市生态城镇化水平逐渐趋同。加强区域生态一体化建设,提高区域生态城镇化水平,是建设美丽中国的有效途径,也是实现区域高质量发展的必然选择。     

碳化温度对牛粪铜和锌形态及生态毒性的影响

通过设置不同的热解温度(350,550和750℃)对牛粪废弃物进行碳化处理,并使用光谱技术手段对牛粪炭的微观特点及Cu、Zn赋存形态进行了分析表征,同时结合淋溶和毒性实验探究了热解温度对牛粪炭生态毒性的影响.结果表明,高温碳化明显改善牛粪孔隙结构,使其比表面积从牛粪原料的1.15m²/g提高至牛粪炭的5.51(350℃)~195.90m²/g(750℃).随着热解温度的提高,牛粪炭pH值从8.18(350℃)提高到了10.14(750℃);牛粪炭中Cu、Zn含量则从牛粪原料中的1.22和1.23mg/g分别升高至18.29~35.11和18.58~31.24mg/g.透射电镜-选区衍射以及X射线能谱分析表明,热解处理可使牛粪中Cu、Zn离子分别转化为副黑铜矿(Cu₄O₃)和红锌矿(ZnO)等金属氧化物,从而明显降低了牛粪炭中水溶态、DTPA提取态以及HNO₃-H₂SO₄提取态的Cu、Zn离子浓度;此外,FTIR分析及混合有机酸浸提实验结果也表明,350℃牛粪炭中酚羟基、烷烃基、羧基、酰胺类等有机官能团通过吸附和络合作用固定未完全转化的Cu离子,而升高热解温度会使得这些官能团显著减少、促进Cu离子的完全转化以及无机物与Cu、Zn离子之间稳定金属氧化物化合键的形成.淋溶和生态毒性实验表明,高于550℃的热解温度能够显著降低牛粪炭中Cu、Zn的溶出率以及生态毒性,是高Cu、Zn含量牛粪废弃物无害化处理的一种推荐优选技术.     

Rural vehicle emission as an important driver for the variations of summertime tropospheric ozone in the Beijing-Tianjin-Hebei region during 2014–2019

Tropospheric ozone (O₃) pollution is increasing in the Beijing-Tianjin-Hebei (BTH) region despite a significant decline in atmospheric fine aerosol particles (PM_2.5) in recent years. However, the intrinsic reason for the elevation of the regional O₃ is still unclear. In this study, we analyzed the spatio-temporal variations of tropospheric O₃ and relevant pollutants (PM_2.5, NO₂, and CO) in the BTH region based on monitoring data from the China Ministry of Ecology and Environment during the period of 2014–2019. The results showed that summertime O₃ concentrations were constant in Beijing (BJ, 0.06 µg/(m³•year)) but increased significantly in Tianjin (TJ, 9.09 µg/(m³•year)) and Hebei (HB, 6.06 µg/(m³•year)). Distinct O₃ trends between Beijing and other cities in BTH could not be attributed to the significant decrease in PM_2.5 (from -5.08 to -6.32 µg/(m³•year)) and CO (from -0.053 to -0.090 mg/(m³•year)) because their decreasing rates were approximately the same in all the cities. The relatively stable O₃ concentrations during the investigating period in BJ may be attributed to a faster decreasing rate of NO₂ (BJ: -2.55 µg/(m³•year); TJ: -1.16 µg/(m³•year); HB: -1.34 µg/(m³•year)), indicating that the continued reduction of NO_x will be an effective mitigation strategy for reducing regional O₃ pollution. Significant positive correlations were found between daily maximum 8 hr average (MDA8) O₃ concentrations and vehicle population and highway freight transportation in HB. Therefore, we speculate that the increase in rural NO_x emissions due to the increase in vehicle emissions in the vast rural areas around HB greatly accelerates regional O₃ formation, accounting for the significant increasing trends of O₃ in HB.     

利用高炉瓦斯泥中的锌制备活性氧化锌的研究

利用高炉炼铁瓦斯泥中的锌,采用火法富集和湿法浸取制取活性氧化锌。考察了温度、时间对火法富集产品中氧化锌含量和原料瓦斯泥中锌挥发率的影响,确定了富集工艺的最佳条件为:在氮气氛围下,温度从常温以10℃/min升温至1 000℃并且在1 000℃下保持1 h,得到的富集产品中氧化锌含量82.24%;瓦斯泥中锌挥发率97%。同时考察了温度、氨水用量、碳酸氢铵用量和液固比等因素对氧化锌浸取率的影响。确定的最佳工艺条件为:浸取温度40℃,氨水用量为理论量的2倍,碳酸氢铵用量为理论量的2倍,液固比4∶1,浸取时间2 h,氧化锌浸取率达99.9%。湿法制得的活性前驱体碱式碳酸锌,经煅烧得到纯度为98.4%的活性氧化锌产品,氧化锌的总回收率达95.3%。     

中国典型脆弱生态区生态系统管理初步研究

我国脆弱生态区分布范围广、类型多,这些地区大都地处偏远,社会环境封闭,生态环境问题突出,开展脆弱生态区的生态系统管理,是脆弱生态区可持续发展的保障。本文系统阐述了我国脆弱生态区的现状及特征、管理的目标与原则、管理的组织实施以及管理手段与措施。     

寒区隧道溶洞安全距离及衬砌冻胀影响规律研究

为了探究寒区溶洞的大小、远近对隧道结构安全的影响规律，依托寒区某高铁岩溶隧道建立三维有限元模型，通过不同工况的模拟得出溶洞距隧道安全距离临界值与溶洞隧道体积比成正比关系，并拟合出安全距离临界值随溶洞与隧道体积比的变化曲线和关系式。探究溶腔积水冻胀力对衬砌结构的影响规律，基于该寒区隧道周边不同位置、远近的溶洞对其影响进行模拟，研究结果表明:隧底处溶洞冻胀力影响最为显著，且距隧底超过10 m时，小型溶腔冻胀力对隧道的影响较小，衬砌变形值渐趋稳定。研究结果可为该寒区隧道溶洞处理提供依据，并为后续类似工程提供借鉴。